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Clayden 2nd ed errata
Principles of Reactivity (CHEM 202)
Emory University
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Errata
Corrections as of March 2016:
Page Line Correction Date 245 Line 5 (from top of page)
“The only way this can happen is if more of the ester converts to the acid” should be “The only way this can happen is if more of the acid converts to the ester”
09/03/
102 Line 2 (from top of page, in main body of text)
"only the carbon 2s and 2px have the right symmetry" should be "only the carbon 2s and 2pz have the right symmetry"
09/03/
102 Line 4 (from top of page, in main body of text)
"leaving the 2py and 2pz " should be "leaving the 2px and 2py"
09/03/
110 Text on right- hand side of artwork at bottom of page (orange font)
“bonding leads to this much gain in energy” should be “bonding leads to this much release of energy”
09/03/
111 Line 2 (from top of page)
“there is a significant gain in energy when the new bond forms” should be "there is a significant energetic advantage when the new bond is formed”
09/03/
114 Last line in blue box
“.. bonded to a more nucleophilic element” should be “.. bonded to a more electropositive element.”
31/07/
128 ChemDraw at bottom of page
Replace with file Ch06-09 31/07/
150 ChemDraw near bottom of page
Replace with file Ch07-29 31/07/
249 Line 16 Put a colon after the word “reaction” 31/07/ 274 4th line under main column figure
change wording to “.. four-membered ring formed by a bridge across a six-membered ring”
31/07/
278 ChemDraw in blue box
Replace with file Ch13-25 31/07/
279 Margin note “See p. 135” ought to be “See p. 134.” 31/07/ 1145 Margin note in blue box
The word “trans” ought to be italicized 31/07/
326 ChemDraw in middle of page
Replace with file Ch14-82 31/07/
426 “Entry 2” in the table
There is a missing space between “alkyne” and the open parenthesis character
31/07/
443 Line 7 from bottom of page
Spelling – “triphenylphopshine” should be "triphenylphosphine”
31/07/
679 Line 5 from top of page
Delete close parenthesis character at the end of this sentence: "E. Corey used a similar idea to make the insect hormone we introduced on p."
31/07/
693 “Further “Reactions of organosulfur compounds ” should be 31/07/
Errata
reading” section “ Reactions of organosulfur compounds ” --- i., all italicized letters in the book title. 875 Line 8 from bottom of page
Insert “by” between “aldehyde” and “the method” 31/07/
932 Final line of text Insert a colon between “stereochemistry” and “one” 31/07/ 935 First blue box on Mustard Gas
Change “Second World War” to “First World War” 31/07/
996 Yellow box, line 3
This sentence needs the word “and” between “electrophilic alkene” and “must be present”
31/07/
1151 Line 4 from bottom of page
“... reaction between then” should be “... reaction between them”
31/07/
1163 Line 2 from bottom of page
“4-hydroxycinamic acid” should be “4- hydroxycinnamic acid”
31/07/
1181 Line 4 from top of page
Missing comma between “molecular modelling” and “physical organic chemistry”
31/07/
Updated: July 2012
Page Line Correction Date 364 18 (half way down page)
Chemdraw figure: the bottom right diagram (of the figure half way down the page) should show a staggered, not an eclipsed, structure (as per the staggered structure of ethane in the margin of the previous page).
Replacement figure:
08/05/
367 Margin table
The heading of the 3rd column (“109˗˗internal angle”). After 109, this should be a minus sign, not an em dash.
08/05/
374 Line 7 of the 2nd blue box
The value ‘0 ppm’ should be ‘0 ppm’ 08/05/
435 5 The cross reference should be to p not p 08/05/ 806 5 ‘Product9’ at the head of the green column should be ‘Product’ 08/05/ 838 3rd set of chemdaw diagrams
Chemdraw figure: ‘X’ needs replacing with ‘N3’ (twice)
Replacement figure:
08/05/
Errata
723 Chemdraw diagrams at bottom of page
The wrong stereochemistry in the attachment to the quinuclidine ring in quinine.
Replacement figure:
23/05/
755 2nd chemdraw diagram at top of page (quinine)
The wrong stereochemistry in the attachment to the quinuclidine ring in quinine.
Replacement figure:
23/05/
780 quinine diagram in margin
The wrong stereochemistry in the attachment to the quinuclidine ring in quinine.
Replacement figure:
23/05/
913 Green box in margin
The reference to Fleming's book should be: 'Ian Fleming (2009) Molecular Orbitals and Organic Chemical Reactions, Student Edition, Wiley-Blackwell’
23/05/
1082 Second chemdraw diagram
The silver carbonate in the diagram should be Ag2CO3 and not AgCO3.
25/06/
Errata
Replacement figure:
Clayden 2nd ed errata
Course: Principles of Reactivity (CHEM 202)
University: Emory University
